• 文献标题:   Studies on the effect of bio-ionic liquid structures on the spontaneous reduction and dispersion stability of graphene oxide in aqueous media
  • 文献类型:   Article
  • 作  者:   SHARMA M, MONDAL D, MUKESH C, PRASAD K
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   CSIR
  • 被引频次:   6
  • DOI:   10.1039/c4ra05552g
  • 出版年:   2014

▎ 摘  要

Treatment of graphene oxide (GO) at elevated temperature with four choline based bio-ionic liquids (Bio-ILs) having counter anions with different nucleophilicity, namely, choline bicarbonate (chol-HCO3), choline hydroxide (chol-OH), choline formate (chol-HCOO) and choline caproate (chol-C5H11COO) resulted in the formation of partially reduced GO (prGO). The prGO formed in the presence of chol-HCOO and chol-C5H11COO had long term dispersion stability in water (>1 year). The results showed that ILs having strong nucleophiles were able to reduce GO to a higher extent with short term dispersion stability of the prGO, while the ILs with weaker nucleophiles gave the formation of prGO with long term dispersion stability in water.