▎ 摘　　要

A graphene oxide-coated capillary was fabricated by using 3-aminopropyltriethoxysilane as the cross-linking agent. It was used for the separation and detection of three endocrinedisrupting chemicals, including bisphenol A, 4-nonylphenol, and 4-octylphenol by capillary electrochromatography. Due to the hydrophobicity, hydrogen bonding, and pi-pi interaction between graphene oxide and the analytes, the three analytes could be well separated in pH = 11.0, 20 mmol/L Na2B4O7-NaOH/methanol mobile phase (50:50, v/v) within 950 s. After preconcentration, the detection limits were 6.7 x 10(-10), 3.3 x 10(-9), and 6.7 x 10(-10) mol/L (S/N = 3) for bisphenol A, nonylphenol, and octylphenol, respectively. The developed method was successfully applied to the determination of the above analytes in water samples. The satisfactory result demonstrated that the graphene oxide coated capillary used in capillary electrochromatography with amperometric detection was convenient to prepare, highly stable, and had good reproducibility.