• 文献标题:   Chemically modified graphene: flame retardant or fuel for combustion?
  • 文献类型:   Article
  • 作  者:   SHI YM, LI LJ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Acad Sinica
  • 被引频次:   42
  • DOI:   10.1039/c0jm02953j
  • 出版年:   2011

▎ 摘  要

Graphene oxide (GO), an oxidized form of graphene, has attracted lots of attention due to its solution processability and chemical reactivity from its functional groups. GO is known as a promising flame retarding nano-additive in polymers. Interestingly, a local hot spot can trigger a rapid and self-propagating reaction to convert GO into a more stable form, reduced-GO (r-GO). However, the presence of potassium salt impurities causes catastrophic reduction (carbon combustion) of GO (r-GO) once these chemically modified graphene materials are triggered by a hot spot. The self-propagating reduction from GO solids is due to its highly energetic nature, suggesting that caution needs to be adopted against a possible fire hazard.