• 文献标题:   Enhanced photothermal effect in reduced graphene oxide in solid-state
  • 文献类型:   Article
  • 作  者:   SAHADEV N, ANAPPARA AA
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF APPLIED PHYSICS
  • ISSN:   0021-8979 EI 1089-7550
  • 通讯作者地址:   Natl Inst Technol Calicut
  • 被引频次:   3
  • DOI:   10.1063/1.4993805
  • 出版年:   2017

▎ 摘  要

We report on a giant photothermal effect in few-layer Reduced Graphene Oxide (RGO) in powder form. Graphite oxide synthesized following modified Hummer's method was thermally exfoliated and reduced to obtain RGO consisting of similar to 8-10 layers. Upon irradiation with an incoherent, broad-band light source (wavelengths ranging from 250 to 450 nm), an enormous photothermal effect was observed. The heat generated by RGO determined from the isothermal differential photocalorimetric technique is as high as similar to 319 W/g resulting from the dominant non-radiative de-excitation of photoexcited electrons due to the absence of a radiative pathway. A practical applicability was demonstrated using a commercial thermoelectric generator wherein upon illumination from a solar-simulator, an open voltage in the mV range was developed, giving a direct proof of the exo-thermic effect in powder RGO upon light illumination. Herewith, we have demonstrated a proofof-concept of photothermal effects in solid-state RGO. Published by AIP Publishing.