• 文献标题:   Ultimate strength, ripples, sound velocities, and density of phonon states of strained graphene
  • 文献类型:   Article
  • 作  者:   DMITRIEV SV, BAIMOVA JA, SAVIN AV, KIVSHAR YS
  • 作者关键词:   graphene, molecular dynamic, structural stability, ripple, phonon spectrum, phonon density of state, sound velocity
  • 出版物名称:   COMPUTATIONAL MATERIALS SCIENCE
  • ISSN:   0927-0256
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   27
  • DOI:   10.1016/j.commatsci.2011.08.019
  • 出版年:   2012

▎ 摘  要

We study the dispersion characteristics of strained graphene using many-body interatomic potentials and find: (i) borders of the structural stability of a flat graphene in the three-dimensional space of the strain components (epsilon(xx), epsilon(yy), epsilon(xy)); (ii) sound velocities of strained graphene; and (iii) phonon density of states (DOS) of strained graphene. The border of structural stability of flat graphene is also presented in the space of components of normal and shear membrane forces (T-x, T-y, T-xy). We find that flat graphene is structurally stable under elastic strain up to 0.3-0.4, but it becomes unstable to a shear strain in the absence of tensile components of strain. Also graphene cannot remain flat under compressive membrane forces because its bending stiffness vanishes. We employ the molecular dynamics simulations to study the post-critical behavior of graphene. We demonstrate that ripples with controllable amplitude and orientation can be generated under simultaneous action of shear and tensile membrane forces. Gaps in the phonon DOS are observed when graphene is strained close to the appearance of ripples. Sound velocities of unstrained graphene do not depend on the propagation direction but application of strain makes graphene anisotropic. One of the sound velocities vanishes at the border of the structural stability of graphene meaning that vanishing of sound velocity (or corresponding elastic constant) predicts impending instability. (C) 2011 Elsevier B. V. All rights reserved.