• 文献标题:   High-Power Supercapacitive Properties of Graphene Oxide Hybrid Films with Highly Conductive Molybdenum Disulfide Nanosheets
  • 文献类型:   Article
  • 作  者:   BYUN S, SIM DM, YU J, YOO JJ
  • 作者关键词:   graphene oxide, hybrid film, molybdenum disulfide, phase transformation, supercapacitor
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   18
  • DOI:   10.1002/celc.201500393
  • 出版年:   2015

▎ 摘  要

By introducing a graphene oxide (GO) sheet as a phase stabilizer and a mechanical supporter, MoS2/GO hybrid films consisting of a high concentration of distorted 1T-MoS2 are successfully fabricated through a post-annealing process in air with the form of a restacked film. After the annealing process, the MoS2 nanosheets undergo direct binding with the oxygen functional groups of GO, maintaining their highly conducting 1T phase and leading to distorted 1T-MoS2 or 1T-MoS2. A hybrid film-based supercapacitor reveals significantly enhanced electrochemical properties, such as an ultrahigh volumetric power density (approximate to 207Wcm(-3)), high volumetric capacitance (approximate to 380Fcm(-3) at 10mVs(-1)), superior rate capability, and a semi-permanent cycle life (95% retention after 10000 cycles) in an aqueous electrolyte.