• 文献标题:   Sensing hydrogen peroxide with a glassy carbon electrode modified with silver nanoparticles, AlOOH and reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   YANG ZY, QI CC, ZHENG XH, ZHENG JB
  • 作者关键词:   transmission electron microscopy, xray diffraction, cyclic voltammetry, nanomaterial, chitosan, boehmite, nonenzymatic sensor
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   NW Univ Xian
  • 被引频次:   26
  • DOI:   10.1007/s00604-016-1743-5
  • 出版年:   2016

▎ 摘  要

A nanocomposite consisting of silver nanoparticles (AgNPs), AlOOH and reduced graphene oxide (rGO) was prepared where gamma-AlOOH was employed to modify rGO to obtain a platform for the growth of dispersed AgNPs. A glassy carbon electrode was modified with the nanocomposite in a chitosan matrix to obtain a nonenzymatic sensor for H2O2 with a working voltage of typically -0.3 V (vs. Ag/AgCl). The morphology and composition of the nanocomposites were characterized by transmission electron microscopy, Raman spectra, X-ray spectrometer and X-ray diffraction. Cyclic voltammetry revealed a wide linear range (5.0 mu M to 4.2 mM), a sensitivity of 115.4 mu A center dot mM(-1) center dot cm(-2) and a low detection limit (1.8 mu M).