• 文献标题:   Green reduction of graphene oxide via Lycium barbarum extract
  • 文献类型:   Article
  • 作  者:   HOU DD, LIU QF, CHENG HF, ZHANG H, WANG S
  • 作者关键词:   lycium barbarum extract, green reduction, graphene oxide, natural reductant
  • 出版物名称:   JOURNAL OF SOLID STATE CHEMISTRY
  • ISSN:   0022-4596 EI 1095-726X
  • 通讯作者地址:   China Univ Min Technol
  • 被引频次:   16
  • DOI:   10.1016/j.jssc.2016.12.008
  • 出版年:   2017

▎ 摘  要

The synthesis of graphene from graphene oxide (GO) usually involves toxic reducing agents that are harmful to human health and the environment. Here, we report a facile approach for effective reduction of GO, for the first time, using Lycium barbarum extract as a green and natural reducing agent. The morphology and de-oxidation efficiency of the reduced graphene were characterized and results showed that Lycium barbarum extract can effectively reduce GO into few layered graphene with a high carbon to oxygen ratio (6.5), comparable to that of GO reduced by hydrazine hydrate (6.6). The possible reduction mechanism of GO may be due to the active components existing in Lycium barbarum fruits, which have high binding affinity to the oxygen containing groups to form their corresponding oxides and other by-products. This method avoided the use of any nocuous chemicals, thus facilitating the mass production of graphene and graphene-based bio-materials.