• 文献标题:   Optimization of glassy carbon electrode based graphene/ferritin/glucose oxidase bioanode for biofuel cell applications
  • 文献类型:   Article
  • 作  者:   INAMUDDIN, AHMAD K, NAUSHAD M
  • 作者关键词:   glassy carbon electrode, ferritin, glucose oxidase, bioanode, bifuel cell
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Aligarh Muslim Univ
  • 被引频次:   20
  • DOI:   10.1016/j.ijhydene.2014.02.171
  • 出版年:   2014

▎ 摘  要

A glassy carbon (GC)/graphene/ferritin/glucose oxidase (GOx) anode was developed by using graphene/ferritin biocomposite as an electron transfer enhancer and mediator, respectively. The electrode exhibited good electrocatalytic activity towards the oxidation of glucose. The electrocatalytic oxidation of glucose using GOx modified electrode increased with increasing the concentration of glucose upto 45 mM. The results showed that the graphene/ferritin biocomposite mediator provides enhancement in electron transfer generated at the active cites of GOx to the electrode. All electrochemical measurements were carried out by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). A saturation current density of 66.5 +/- 2 mA cm(-2) at scan rate 100 mV s(-1) for the oxidation of 45 mM glucose was achieved. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.