▎ 摘　　要

Response surface methodology was successfully used to optimize the amounts of chitosan (CS), polyethyleneimine (PEI), graphene oxide (GO), and glutaraldehyde (GLA) to produce a multifunctional nano composite membrane coating able to remove positively and negatively charged heavy metals, such as Cr(VI) and Cu(II). Batch experiments with different concentrations of the four coating components (GO, CS, PEI, and GLA) on cellulose membranes were carried out with solutions containing 10 ppm Cr(VI) and Cu(II) ions. Reduced quadratic equations for the Cr(VI) and Cu(II) removal were obtained based on the observed results of the batch experiments. The numerical analysis resulted in an optimized solution of soaking for 30 min in CS, 1.95% PEI, 1000 ppm GO, and 1.68% GLA with predicted removal of 90 +/- 10 and 30 +/- 3% for Cr(VI) and Cu(II), respectively, with a desirability of 0.99. This mathematically optimized solution for the coating was experimentally validated. To determine the best membrane material for the coating, stability of the nanocomposite coating was determined using attenuated total reflectance-infrared spectroscopy in eight membrane materials before and after exposure to four solutions with different water chemistries. The glass microfiber (GMF) membranes were determined to be one of the best materials to receive the coating. Then, the coated GMF filter was further investigated for the removal of Cr(VI) and Cu(II) in single and binary component solutions. The results showed that the coatings were able to remove successfully both heavy metal ions, suggesting its ability to remove positively and negatively charged ions from water.