• 文献标题:   Rheological behavior of fresh cement pastes with a graphene oxide additive
  • 文献类型:   Article
  • 作  者:   WANG Q, WANG J, LU CX, CUI XY, LI SY, WANG X
  • 作者关键词:   graphene oxide, cement paste, rheological property, flocculation structure
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827
  • 通讯作者地址:   Beijing Univ Civil Engn Architecture
  • 被引频次:   10
  • DOI:   10.1016/S1872-5805(16)60033-1
  • 出版年:   2016

▎ 摘  要

The theological properties and morphology of fresh cement pastes with different contents of graphene oxide (GO) were investigated by a rheometer and a laser confocal scanning microscope, respectively. The theological data were fitted by the Modified-Bingham (M-B) model and Herschel-Bulkley (H-B) model. A mechanism for the effect of GO on the rheological properties is proposed. Results sheiw that the cement particles are re-agglomerated and new flocculation structures are generated by the addition of GO. The new flocculation structures significantly alter the rheological properties of the pastes. The degree of re-agglomeration and the number of new flocculation structures increase with increasing GO content, leading to a sharp increase in the yield stress, plastic viscosity and the area of the hysteresis loop. GO can effectively reduce the degree of shear-thickening, and increase the critical shear rate and the stability of the pastes.