• 文献标题:   Electrospun reduced graphene oxide/TiO2/poly(acrylonitrile-co-maleic acid) composite nanofibers for efficient adsorption and photocatalytic removal of malachite green and leucomalachite green
  • 文献类型:   Article
  • 作  者:   DU FY, SUN LS, HUANG ZJ, CHEN ZY, XU ZG, RUAN GH, ZHAO CX
  • 作者关键词:   electrospinning, composite nanofiber, adsorption, photocatalytic degradation, dye removal
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:   Changsha Univ
  • 被引频次:   11
  • DOI:   10.1016/j.chemosphere.2019.124764
  • 出版年:   2020

▎ 摘  要

Electrospun reduced graphene oxide/TiO2/poly(acrylonitrile-co-maleic acid) composite nanofibers (E-spun RGO/TiO2/PANCMA NFs) were fabricated using electrospinning of the dispersive solution of PANCMA, GO and TiO(2)followed by post-chemical reduction. The obtained composite nanofibers were compressed in a dialyzer and then used to absorb and degrade malachite green (MG) and leucomalachite green (LMG) from aqueous solution. Compared to the E-spun TiO2/PANCMA and GO/TiO2/PANCMA NFs, the E-spun RGO/TiO2/PANCMA NFs exhibited higher adsorption capacity and photocatalytic degradation ability. Under optimized conditions, 90.6% of MG and 93.7% of LMG from 50 mL aqueous sample solution were adsorbed on the RGO/TiO2/PANMA NFs (3.0 mg fibers) in 2.0 min, and subsequent the 91.4% and 95.2% of MG and LMG adsorbed on the NFs were degradated in 60 min under UV irradiation, respectively. In addition, the E-spun RGO/TiO2/PANMA NFs exhibited good reusability and could be reused in multiple cycles of operations for adsorption and photocatalytic degradation of MG and LMG. This work demonstrated that the electrospun composite nanofibers are promising materials for removal of pollutants from environmental water samples. (C) 2019 Elsevier Ltd. All rights reserved.