• 文献标题:   Graphene Oxide Shells on Plasmonic Nanostructures Lead to High-Performance Photovoltaics: A Model Study Based on Dye-Sensitized Solar Cells
  • 文献类型:   Article
  • 作  者:   JANG YH, RANI A, QUAN LN, ADINOLFI V, KANJANABOOS P, OUELLETTE O, SON T, JANG YJ, CHUNG K, KWON H, KIM D, KIM DH, SARGENT EH
  • 作者关键词:  
  • 出版物名称:   ACS ENERGY LETTERS
  • ISSN:   2380-8195
  • 通讯作者地址:   Ewha Womans Univ
  • 被引频次:   10
  • DOI:   10.1021/acsenergylett.6b00612
  • 出版年:   2017

▎ 摘  要

The incorporation of plasmonic nanoparticles (NPs) into photovoltaic devices can increase light absorption and in turn improve solar cell performance. The graphene oxide-encapsulated gold NPs (Au@GO NPs) are designed and incorporated into photoanodes to demonstrate plasmonic dye-sensitized solar cells. The coupling between GO and the Au NPs has the beneficial effect of extending solar spectral utilization in the long-wavelength portion of the visible spectrum. In addition, GO encapsulation reduces charge recombination on the surface of the NPs and facilitates improved charge transport. As a result, champion devices with plasmonic photoanodes containing Au@GO NPs deliver a power conversion efficiency that reaches 9.1%. This corresponds to an enhancement in photocurrent and power conversion efficiency of 19 and 17%, respectively, compared to control devices.