▎ 摘　　要

In this study, we found that the work functions (Phi(w)) of solution-processable, functional graphene/carbon nanotube-based transparent conductors were readily manipulated, varying between 5.1 and 3.4 eV, depending on the nature of the doping alkali carbonate salt. We used the graphene-based electrodes possessing lower values of Phi(w) as cathodes in Inverted-architecture polymer photovoltaic devices to effectively collect electrons, giving rise to an optimal power conversion efficiency of 1.27%.