• 文献标题:   Superior Electrochemical Performance of Sulfur/Graphene Nanocomposite Material for High-Capacity Lithium-Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   WANG B, LI KF, SU DW, AHN HJ, WANG GX
  • 作者关键词:   electrochemistry, energy conversion, graphene, lithium, sulfur
  • 出版物名称:   CHEMISTRYAN ASIAN JOURNAL
  • ISSN:   1861-4728
  • 通讯作者地址:   Univ Technol Sydney
  • 被引频次:   52
  • DOI:   10.1002/asia.201200004
  • 出版年:   2012

▎ 摘  要

Sulfur/graphene nanocomposite material has been prepared by incorporating sulfur into the graphene frameworks through a melting process. Field-emission scanning electron microscope analysis shows a homogeneous distribution of sulfur in the graphene nanosheet matrix. The sulfur/graphene nanocomposite exhibits a super-high lithium-storage capacity of 1580 mAh?g-1 and a satisfactory cycling performance in lithiumsulfur cells. The enhancement of the reversible capacity and cycle life could be attributed to the flexible graphene nanosheet matrix, which acts as a conducting medium and a physical buffer to cushion the volume change of sulfur during the lithiation and delithiation process. Graphene-based nanocomposites can significantly improve the electrochemical performance of lithiumsulfur batteries.