• 文献标题:   Au-Pt bimetallic nanoparticles supported on functionalized nitrogen-doped graphene for sensitive detection of nitrite
  • 文献类型:   Article
  • 作  者:   LI Z, AN ZZ, GUO YY, ZHANG KN, CHEN XL, ZHANG DX, XUE ZH, ZHOU XB, LU XQ
  • 作者关键词:   nitrogendoped graphene, goldplatinum bimetallic nanoparticle, sensor, nitrite, electrocatalytic oxidation
  • 出版物名称:   TALANTA
  • ISSN:   0039-9140 EI 1873-3573
  • 通讯作者地址:   Northwest Normal Univ
  • 被引频次:   21
  • DOI:   10.1016/j.talanta.2016.09.033
  • 出版年:   2016

▎ 摘  要

In this work, we report a novel Au-Pt bimetallic nanoparticles (Au-PtNPs) decorated on the surface of nitrogen doped graphene (NG) functionalized with 1, 3, 6, 8-pyrene tetra sulfonic acid sodium salt (PyTS) by direct electrodeposition method. The results of scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and electrochemical impendence spectrum (EIS) reveal that the Au-PtNPs were successfully anchored on the surface of NG sheets with a diameter of 20-40 nm. Further, the prepared Au-PtNPs/PyTS-NG nanocomposite exhibits superior catalytic activity for the oxidation of nitrite. Under optimal experimental conditions, an amperometric sensor with a linear range of 0.5-1621 mu M and a detection limit of 0.19 mu M (S/N=3) for the detection of nitrite was set up and applied to real samples.