• 文献标题:   Ionic liquid crystal-assisted synthesis of PtAg nanoflowers on reduced graphene oxide and their enhanced electrocatalytic activity toward oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   LV JJ, FENG JX, LI SS, WANG YY, WANG AJ, ZHANG QL, CHEN JR, FENG JJ
  • 作者关键词:   ionic liquid crystal, flowerlike bimetallic alloy, reduced graphene oxide, oxygen reduction reaction
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   28
  • DOI:   10.1016/j.electacta.2014.04.077
  • 出版年:   2014

▎ 摘  要

A simple and facile one-pot solvothermal method is developed for preparation of flower-like PtAg alloys uniformly supported on reduced graphene oxide nanosheets (flower-like PtAg/RGOs). Ionic liquid crystal (1-hexadecyl-2,3-dimethylimidazolium bromide, [C(16)MMIm]13r) is used as a capping agent and a structure directing agent. The as-prepared nanocomposites show the larger electrochemically active surface area, better catalytic activity, higher methanol tolerant activity, and longer-term durability for oxygen reduction reaction, compared with commercial Pt black, Pt-C (10 wt %), and RGOs catalysts. (C) 2014 Elsevier Ltd. All rights reserved.