• 文献标题:   NiMn2O4 spinel binary nanostructure decorated on three-dimensional reduced graphene oxide hydrogel for bifunctional materials in non-enzymatic glucose sensor
  • 文献类型:   Article
  • 作  者:   NGO YLT, SUI LJ, AHN W, CHUNG JS, HUR SH
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   12
  • DOI:   10.1039/c7nr07748c
  • 出版年:   2017

▎ 摘  要

Nickel-manganese spinel oxide (NiMn2O4) was hybridized with reduced graphene oxide hydrogel (rGOH) via a facile solvothermal process and a highly porous three-dimensional (3D) structure was constructed. NiMn2O4/rGOH exhibited excellent electrochemical performance due to the high specific surface area, excellent electrocatalytic activity, and enhanced electrical conductivity due to the synergetic effects between the two components. The NiMn2O4/rGOH exhibited excellent glucose sensing performance with high sensitivity (1310.8 mu A mM(-1) cm(-2)), a wide linear range (2 mu M-20 mM), rapid response time (<3.5 s), and anti-interference properties. Furthermore, it also showed excellent supercapacitor performance with a high capacitance (396.85 F g(-1)) and excellent energy and power density on account of the large surface area and pseudo-capacitor behavior of NiMn2O4. A self-powered glucose sensor can be fabricated with NiMn2O4/rGOH as both supercapacitor and glucose sensing electrodes.