• 文献标题:   Statistical analysis of the electrocatalytic activity of Pt nanoparticles supported on novel functionalized reduced graphene oxide-chitosan for methanol electrooxidation
  • 文献类型:   Article
  • 作  者:   EKRAMIKAKHKI MS, ABBASI S, FARZANEH N
  • 作者关键词:   pt nanoparticle, methanol oxidation, anodic current density, peak potential, statistical analysi
  • 出版物名称:   ELECTRONIC MATERIALS LETTERS
  • ISSN:   1738-8090 EI 2093-6788
  • 通讯作者地址:   Esfarayen Univ Technol
  • 被引频次:   6
  • DOI:   10.1007/s13391-017-7052-2
  • 出版年:   2018

▎ 摘  要

The purpose of this study is to statistically analyze the anodic current density and peak potential of methanol oxidation at Pt nanoparticles supported on functionalized reduced graphene oxide (RGO), using design of experiments methodology. RGO is functionalized with methyl viologen (MV) and chitosan (CH). The novel Pt/MV-RGO-CH catalyst is successfully prepared and characterized with transmission electron microscopy (TEM) image. The electrocatalytic activity of Pt/MV-RGOCH catalyst is experimentally evaluated for methanol oxidation. The effects of methanol concentration and scan rate factors are also investigated experimentally and statistically. The effects of these two main factors and their interactions are investigated, using analysis of variance test, Duncan's multiple range test and response surface method. The results of the analysis of variance show that all the main factors and their interactions have a significant effect on anodic current density and peak potential of methanol oxidation at alpha = 0.05. The suggested models which encompass significant factors can predict the variation of the anodic current density and peak potential of methanol oxidation. The results of Duncan's multiple range test confirmed that there is a significant difference between the studied levels of the main factors.