• 文献标题:   Experimental and computational studies of sonochemical assisted anchoring of carbon quantum dots on reduced graphene oxide sheets towards the photocatalytic activity
  • 文献类型:   Article
  • 作  者:   ASHRITHA MG, RONDIYA SR, CROSS RW, DZADE NY, DHOLE SD, HAREESH K, SUNITHA DV
  • 作者关键词:   carbon quantum dot, reduced graphene oxide, sonochemical method, photocatalytic activity, density functional theory
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   16
  • DOI:   10.1016/j.apsusc.2021.148962 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Herein, carbon quantum dots (CQDs) are anchored on reduced graphene oxide (rGO) sheets by sonochemical assisted method. The developed carbon quantum dots/reduced graphene oxide (CQDs/rGO) catalyst shows enhancement in the photocatalytic degradation of methylene blue and methyl orange under visible light compared to that of individual CQDs and rGO components. The improved performance of the CQDs/rGO catalyst has been attributed to efficient separation of photogenerated charge carriers as studied by photoluminescence studies and to increase in the surface area as studied by Brunauer-Emmett-Teller method. The photocatalytic degradation is studied in detail by varying catalyst loading, dye concentration and the rate constant is determined by first order kinetics. The enhancement in photocatalytic activity of CQDs/rGO catalyst is validated by first principles density functional theory (DFT) calculations which shows the enrichment in density of states thereby decreasing the work function.