• 文献标题:   Three-dimensionally macroporous graphene-supported Fe3O4 composite as anode material for Li-ion batteries with long cycling life and ultrahigh rate capability
  • 文献类型:   Article
  • 作  者:   MA DL, YUAN S, CAO ZY
  • 作者关键词:   liion batteries libs, conversion reaction, highperformance anode, fe3o4, graphene
  • 出版物名称:   CHINESE SCIENCE BULLETIN
  • ISSN:   1001-6538 EI 1861-9541
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   13
  • DOI:   10.1007/s11434-014-0307-5
  • 出版年:   2014

▎ 摘  要

Fe3O4 is an attractive conversion reaction-based anode material with high theoretical capacity (928 mA h g(-1)). However, the poor cycling and rate performance hinder its applications in Li-ion batteries. In this work, we report an effective strategy to synthesize three-dimensionally macroporous graphene-supported Fe3O4 hybrid composite. Benefiting from advantage of the special structure, the hybrid composite exhibits excellent Li+ storage performance, delivering a high reversible capacity of 980 mA h g(-1) at the current density of 4 A g(-1) even after 470 cycles and ultrahigh rate capability (293 mA h g(-1) even at current density of 20 A g(-1)).