• 文献标题:   Polyethylene glycol/polyvinyl butyral/graphene nanoplates as composite phase-change materials with high thermal conductivity
  • 文献类型:   Article
  • 作  者:   XU CL, WANG WZ, ZHANG H, FANG GY
  • 作者关键词:   composite phasechange material, thermal performance, polyethylene glycol, polyvinyl butyral, graphene nanoplate
  • 出版物名称:   SOLAR ENERGY MATERIALS SOLAR CELLS
  • ISSN:   0927-0248 EI 1879-3398
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.solmat.2022.112093 EA NOV 2022
  • 出版年:   2023

▎ 摘  要

Composite phase-change materials (CPM) were prepared using polyethylene glycol (PG), polyvinyl butyral (PB) and graphene nanoplates (GP). PG is a phase-change material (PM), PB is used as supporting material, and GP is an additive with high thermal conductivity. The results of Fourier transformation infrared spectroscope (FT-IR) and X-ray diffractometer (XRD) show that there is no chemical reaction among the PB, PG and GP. The CPM was observed with a laminar structure by scanning electronic microscope (SEM). Differential scanning calorimeter (DSC), thermogravimetric analyzer (TGA) and transient hot-wire conductivity meter were used to measure thermal performance of the CPM. The experimental results indicate that CPM3 has best thermal performance. The CPM3 containing 5 wt% GP has thermal conductivity of 2.04 W/(m.K), 8.87 times that of pure PG. The melting temperature and latent heat of the CPM3 are 58.75 degrees C and 147.81 J/g. Thermal cycling experiments demonstrate the CPM3 possesses good thermal reliability. Therefore, it has application prospects in solar energy utilization, building energy conservation and waste heat recovery.