• 文献标题:   Space-confined strategy to stabilize the lithium storage in the graphene and silver nanoparticles (AgNPs@GO) composite anode of lithium metal batteries
  • 文献类型:   Article
  • 作  者:   KONG YF, MA Z, ZHENG DP, YANG CH, ZHENG JR, HE GP, NAN JM
  • 作者关键词:   agnps@go composite, energy storage conversion, spaceconfined, nanoparticle
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   South China Normal Univ
  • 被引频次:   1
  • DOI:   10.1016/j.matlet.2019.05.068
  • 出版年:   2019

▎ 摘  要

A flower-like oxidized graphene and metal silver nanoparticles composite (AgNPs@GO) was prepared by a spray-drying and annealing process. The AgNPs@GO exhibits three-dimensional (3D) multi-layer heterojunction structure and high surface area, which can reduce the overpotential of lithium deposition, decrease lithium dendrites, and stabilize lithium storage. Especially, an excellent electrochemical performance is obtained due to the space-confined feature of AgNPs@GO structure. At 0.25 mA cm(-2) for 0.5 mAh cm(-2), the AgNPs@GO-300 reveals a hysteresis voltage of only 32.3 mV at the 10th cycle and a stable coulombic efficiency of 97.1% after nearly 1000 h cycles, indicating promising prospects as lithium metal anode. (C) 2019 Elsevier B.V. All rights reserved.