• 文献标题:   Enhanced ferromagnetism in edge enriched holey/lacey reduced graphene oxide nanoribbons
  • 文献类型:   Article
  • 作  者:   SAHU V, MAURYA VK, SINGH G, PATNAIK S, SHARMA RK
  • 作者关键词:   holey graphene nanoribbon, ferromagnetism, high edge density, point defect
  • 出版物名称:   MATERIALS DESIGN
  • ISSN:   0264-1275 EI 1873-4197
  • 通讯作者地址:   Univ Delhi
  • 被引频次:   3
  • DOI:   10.1016/j.matdes.2017.07.005
  • 出版年:   2017

▎ 摘  要

Incorporation ofmagnetism in graphene based compounds holds great promise for potential spintronic applications. By optimizing point defects and high edge density of defects, we report many-fold increase in the ferromagnetic saturation moment in lacey/holey reduced graphene oxide nanoribbons (LRGONR) as compared to other graphene derivatives. The samples were synthesized using chemical unzipping methodology. Detailed structural and morphological characterizations are discussed that include XRD, Raman, SEM, HRTEM and XPS measurements. Brilluoin function analysis to magnetization data reflects best fit for J= 7/2with a saturation moment of 1.1 emu/g. The microscopic origin of magnetization in LRGONR is assigned to high edge defect density which has also been correlated to microstructure. (C) 2017 Elsevier Ltd. All rights reserved.