• 文献标题:   Metal Oxide-Coated Three-Dimensional Graphene Prepared by the Use of Metal-Organic Frameworks as Precursors
  • 文献类型:   Article
  • 作  者:   CAO XH, ZHENG B, RUI XH, SHI WH, YAN QY, ZHANG H
  • 作者关键词:   composite material, lithiumion batterie, metalorganic framework, photocatalysi, threedimensional graphene network
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   189
  • DOI:   10.1002/anie.201308013
  • 出版年:   2014

▎ 摘  要

A simple method for the preparation of metal-oxide-coated three-dimensional (3D) graphene composites was developed. The metal-organic frameworks (MOFs) that served as the precursors of the metal oxides were first synthesized on the 3D graphene networks (3DGNs). The desired metal oxide/3DGN composites were then obtained by a two-step annealing process. As a proof-of-concept application, the obtained ZnO/3DGN and Fe2O3/3DGN materials were used in a photocatalytic reaction and a lithium-ion battery, respectively. We believe this method could be extended to the synthesis of other metal oxide/3DGN composites with 3D structures simply through the appropriate choice of specific MOFs as precursors.