• 文献标题:   Plasmon-Enhanced Photocurrent Generation from Click-Chemically Modified Graphene
  • 文献类型:   Article
  • 作  者:   YENCHALWAR SG, DEVARAPALLI RR, DESHMUKH AB, SHELKE MV
  • 作者关键词:   gold, graphene, nanoparticle, photophysic, surface plasmon resonance
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   CSIR Natl Chem Lab
  • 被引频次:   7
  • DOI:   10.1002/chem.201400403
  • 出版年:   2014

▎ 摘  要

The visible-light response of Au nanoparticles (AuNPs) assembled on rGO through different molecular bridges was investigated by transient photocurrent generation. We prepared rGO with two self-assembled monolayers (SAMs), one linear and the other with aromatic triazoles through a click cycloaddition reaction. A fivefold photocurrent enhancement was observed for triazole linkers over the aminopropyltrimethoxysilane (APTMS) linker. Cyclic voltammetry (CV) and impedance measurements also suggest fast electron transfer on account of the low resistance offered by the click-modified rGO surface whereby introduction of triazoles offers the efficient bridge between the donor AuNPs and acceptor rGO.