• 文献标题:   2D Ca3Sn2S7 Chalcogenide Perovskite: A Graphene-Like Semiconductor with Direct Bandgap 0.5 eV and Ultrahigh Carrier Mobility 6.7 x 10(4) cm(2) V-1 s(-1)
  • 文献类型:   Article
  • 作  者:   DU J, SHI JJ
  • 作者关键词:   ca3sn2s7 monolayer, direct bandgap semiconductor, graphenelike linear electronic dispersion, strong optical absorption, ultrahigh carrier mobility
  • 出版物名称:   ADVANCED MATERIALS
  • ISSN:   0935-9648 EI 1521-4095
  • 通讯作者地址:   Peking Univ
  • 被引频次:   4
  • DOI:   10.1002/adma.201905643 EA NOV 2019
  • 出版年:   2019

▎ 摘  要

Graphene, a star 2D material, has attracted much attention because of its unique properties including linear electronic dispersion, massless carriers, and ultrahigh carrier mobility (10(4)-10(5) cm(2) V-1 s(-1)). However, its zero bandgap greatly impedes its application in the semiconductor industry. Opening the zero bandgap has become an unresolved worldwide problem. Here, a novel and stable 2D Ruddlesden-Popper-type layered chalcogenide perovskite semiconductor Ca3Sn2S7 is found based on first-principles GW calculations, which exhibits excellent electronic, optical, and transport properties, as well as soft and isotropic mechanical characteristics. Surprisingly, it has a graphene-like linear electronic dispersion, small carrier effective mass (0.04 m(0)), ultrahigh room-temperature carrier mobility (6.7 x 10(4) cm(2) V-1 s(-1)), Fermi velocity (3 x 10(5) m s(-1)), and optical absorption coefficient (10(5) cm(-1)). Particularly, it has a direct quasi-particle bandgap of 0.5 eV, which realizes the dream of opening the graphene bandgap in a new way. These results guarantee its application in infrared optoelectronic and high-speed electronic devices.