• 文献标题:   Two-Dimensional CuO Inside the Supportive Bilayer Graphene Matrix
  • 文献类型:   Article
  • 作  者:   KVASHNIN DG, KVASHNIN AG, KANO E, HASHIMOTO A, TAKEGUCHI M, NARAMOTO H, SAKAI S, SOROKIN PB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Natl Univ Sci Technol MISiS
  • 被引频次:   1
  • DOI:   10.1021/acs.jpcc.9b05353
  • 出版年:   2019

▎ 摘  要

New two-dimensional (2D) copper monoxide located at the pore in a bilayer graphene matrix is investigated in both theoretical and experimental ways. Strict analysis of the lattice stability with respect to the magnetic state reveals that the CuO monolayer displays an antiferromagnetic rectangular structure as a favorable state. It is shown that 2D CuO can be confined in a bilayered graphene pore terminated with Cu atoms forming spin-polarized states on the graphene/CuO interface. It is found that the co-presence of Cu and O atoms around the bilayered graphene edge plays an essential role in the 2D CuO formation process.