▎ 摘　　要

We report a facile chemical method for fabricating holey graphene by catalytic oxidation of highly ordered pyrolytic graphite (HOPG) using an Fe-III porphyrin complex-based covalent organic framework (COF) as a bifunctional surface catalyst-template. We demonstrate regular hole formation after oxidation with H2O2 and NaOCl, COF removal, and HOPG exfoliation.