• 文献标题:   Ultrathin Ni-Co double hydroxide nanosheets with conformal graphene coating for highly active oxygen evolution reaction and lithium ion battery anode materials
  • 文献类型:   Article
  • 作  者:   SHI JH, DU NX, ZHENG WJ, LI XC, DAI Y, HE GH
  • 作者关键词:   nico hydroxide, oxygen evolution reaction, lithium ion battery, graphene, electrodeposition
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Dalian Univ Technol
  • 被引频次:   33
  • DOI:   10.1016/j.cej.2017.06.080
  • 出版年:   2017

▎ 摘  要

Ultrathin graphene wrapped Ni-Co double hydroxide nanosheets (similar to 10 nm) were synthesized by a facile and rapid electrodeposition process, and evaluated as electrocatalysts for oxygen evolution reaction (OER) and anode materials for Li-ion batteries. The conformal graphene coating on the nanosheets significantly increased the conductivity and surface area of the Ni-Co double hydroxide electrodes. As the OER electrocatalyst, the Ni-Co graphene hybrids show a superior catalytic activity with a small Tafel slope of 67 mV per decade due to the synergy between the abundant active sites of the Ni-Co hydroxides and the conductive graphene coating, and a modest overpotential of 280 mV at a current density of 10 mA cm(-2). Impressively, the electrodes exhibit an excellent stability evaluated by chronopotentiometry under a high current density of 30 mA cm(-2) for 12 h. As Li-ion battery anode, the materials show a high specific capacity of 373 mA h g(-1) up to 500 cycles even at a high current density of 1000 mA g(-1). This study provides a new strategy to develop robust and affordable alternative OER catalyst and anode material for high-performance lithium ion batteries. (C) 2017 Elsevier B.V. All rights reserved.