• 文献标题:   Pd nanoparticles supported on Fe3O4@amine-functionalized graphene composite and catalytic performance in Sonogashira cross-coupling reactions
  • 文献类型:   Article
  • 作  者:   KIM M, KANG H, PARK KH
  • 作者关键词:   catalyst, pd nanopartide, sonogashira crosscoupling, graphene, fe3o4
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   21
  • DOI:   10.1016/j.catcom.2015.09.032
  • 出版年:   2015

▎ 摘  要

In this study, a core-shell Fe3O4@amine-functionalized graphene (Fe3O4@GON) composite was prepared as a support for the immobilization of Pd nanopartides. The graphene oxide (GO) shell was aminated by a condensation reaction between GO and a polyamine. The Pd nanoparticles were immobilized on Fe3O4@GON using sonochemical method without additional reducing agents. The prepared Pd/Fe3O4@GON composite was characterized using TEM, XRD, XPS, ICP-OES and EDS. The catalytic activity of Pd/Fe3O4@GON in heterogeneous Sonogashira cross-coupling reactions between various aryl iodides and terminal acetylenes was investigated. (C) 2015 Elsevier B.V. All rights reserved.