• 文献标题:   GRAPHENE OXIDE AS RECYCLABLE CATALYST FOR ONE-POT SYNTHESIS OF alpha-AMINOPHOSPHONATES
  • 文献类型:   Article
  • 作  者:   DHOPTE KB, RAUT DS, PATWARDHAN AV, NEMADE PR
  • 作者关键词:   aldehyde, amine, aminophosphonate, carbocatalyst, graphene oxide
  • 出版物名称:   SYNTHETIC COMMUNICATIONS
  • ISSN:   0039-7911 EI 1532-2432
  • 通讯作者地址:   Inst Chem Technol
  • 被引频次:   11
  • DOI:   10.1080/00397911.2014.989447
  • 出版年:   2015

▎ 摘  要

We report the synthesis of -aminophosphonates from aromatic aldehydes, aromatic and aliphatic amines, and trimethylphosphite (Kabachnik-Fields reaction) using a carbocatalyst, graphene oxide, at room temperature with excellent yield and recyclability. Enhanced catalytic activity of graphene oxide as compared to other catalysts studied is possibly due to the presence of carboxylic acid and hydroxyl groups.