• 文献标题:   Anomalous diffusion of single metal atoms on a graphene oxide support
  • 文献类型:   Article
  • 作  者:   FURNIVAL T, LEARY RK, TYO EC, VAJDA S, RAMASSE QM, THOMAS JM, BRISTOWE PD, MIDGLEY PA
  • 作者关键词:   anomalous diffusion, single atom catalyst, stem, graphene oxide
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Univ Cambridge
  • 被引频次:   9
  • DOI:   10.1016/j.cplett.2017.04.071
  • 出版年:   2017

▎ 摘  要

Recent studies of single-atom catalysts open up the prospect of designing exceptionally active and environmentally efficient chemical processes. The stability and durability of such catalysts is governed by the strength with which the atoms are bound to their support and their diffusive behaviour. Here we use aberration-corrected STEM to image the diffusion of single copper adatoms on graphene oxide. We discover that individual atoms exhibit anomalous diffusion as a result of spatial and energetic disorder inherent in the support, and interpret the origins of this behaviour to develop a physical picture for the surface diffusion of single metal atoms. (C) 2017 Elsevier B.V. This is an open access article under the CC BY license.