• 文献标题:   Ruthenium Oxide/Reduced Graphene Oxide Nanoribbon Composite and Its Excellent Rate Capability in Supercapacitor Application
  • 文献类型:   Article
  • 作  者:   WANG RJ, JIA PF, YANG YY, AN N, ZHANG YD, WU HY, HU ZG
  • 作者关键词:   ruthenium oxide, graphene oxide nanoribbon, the hummers method, symmetric supercapacitor
  • 出版物名称:   CHINESE JOURNAL OF CHEMISTRY
  • ISSN:   1001-604X EI 1614-7065
  • 通讯作者地址:   Northwest Normal Univ
  • 被引频次:   15
  • DOI:   10.1002/cjoc.201500595
  • 出版年:   2016

▎ 摘  要

Chemical oxidation is used to cut and unzip multi- walled carbon nanotubes in the transverse direction and the axial direction to form graphene oxide nanoribbon ( GONR). Ruthenium oxide/ reduced graphene oxide nanoribbon composite ( RuO2/ rGONR) with a 72.5 wt% RuO2 loading is synthesized through an aqueous- phase reaction, in which GONR is served as starting material, followed by mild thermal treatment in ambient air. The resulting RuO2/ rGONR composite achieves specific capacitance up to 677 F center dot g(-1) at the current density of 1 A center dot g(-1) in three- electrode system using 1 mol center dot L-1 H2SO4 as electrolyte. The resultant electrode exhibits an excellent rate capability ( 91.8% retention rate at 20 A center dot g(-1)). Especially, the symmetric supercapacitor assembled on the basis of RuO2/ rGONR electrode delivers high energy density ( 16.2 Wh center dot kg. 1) even at the power density of 9885 W center dot kg(-1), which is very essential for supercapacitors.