• 文献标题:   Graphene oxide doped poly(vinylidene fluoride-co-hexafluoropropylene) gel electrolyte for lithium ion battery
  • 文献类型:   Article
  • 作  者:   WANG CJ, SHEN WZ, LU J, GUO SW
  • 作者关键词:   poly vinylidene fluoridecohexafluoropropylene, graphene oxide, polymer membrane, polymer electrolyte, lithiumion battery
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   6
  • DOI:   10.1007/s11581-017-2037-6
  • 出版年:   2017

▎ 摘  要

Gel poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) polymer electrolytes doped with graphene oxide (GO) (GO/PVDF-HFP) were designed and fabricated through a phrase inversion method and followed by LiPF6 solution uptake. It was demonstrated that the as-prepared GO/PVDF-HFP polymer electrolytes have uniform porous morphologies, and their crystalline state, thermal stability, interfacial resistance, and electrolyte uptake and retention capabilities can be tuned by varying the GO contents. Further, it was found that the GO can prominently enhance the ionic conductivity of the GO/PVDF-HFP polymer electrolyte. The electrochemical property measurements show that the lithium ion batteries using as-prepared GO/PVDF-HFP polymer electrolytes afford admirable charge/discharge rate and cycle stability.