• 文献标题:   Graphene on Ru(0001): a corrugated and chiral structure
  • 文献类型:   Article
  • 作  者:   MARTOCCIA D, BJORCK M, SCHLEPUTZ CM, BRUGGER T, PAULI SA, PATTERSON BD, GREBER T, WILLMOTT PR
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF PHYSICS
  • ISSN:   1367-2630
  • 通讯作者地址:   Paul Scherrer Inst
  • 被引频次:   69
  • DOI:   10.1088/1367-2630/12/4/043028
  • 出版年:   2010

▎ 摘  要

We present a structural analysis of the graphene/Ru(0001) system obtained by surface x-ray diffraction. The data were fitted using Fourier-series-expanded displacement fields from an ideal bulk structure plus the application of symmetry constraints. The shape of the observed superstructure rods proves a reconstruction of the substrate, induced by strong bonding of graphene to ruthenium. Both the graphene layer and the underlying substrate are corrugated, with peak-to-peak heights of (0.82 +/- 0.15)angstrom and (0.19 +/- 0.02)angstrom for graphene and the topmost Ru-atomic layer, respectively. The Ru corrugation decays slowly over several monolayers into the bulk. The system also exhibits chirality, whereby in-plane rotations of up to 2.0 degrees in those regions of the superstructure where the graphene is weakly bound are driven by elastic energy minimization.