• 文献标题:   Bi2MoO6 co-modified by reduced graphene oxide and palladium (Pd2+ and Pd-0) with enhanced photocatalytic decomposition of phenol
  • 文献类型:   Article
  • 作  者:   MENG XC, ZHANG ZS
  • 作者关键词:   photocatalysi, graphene, spr, bi2moo6, palladium
  • 出版物名称:   APPLIED CATALYSIS BENVIRONMENTAL
  • ISSN:   0926-3373 EI 1873-3883
  • 通讯作者地址:   Univ Ottawa
  • 被引频次:   50
  • DOI:   10.1016/j.apcatb.2017.01.033
  • 出版年:   2017

▎ 摘  要

A ternary Bi2MoO6 photocatalyst composite was hybridized for the first time, with reduced graphene oxide (rGO) and palladium (Pd) nanoparticles decorated on the surface. As-prepared composites exhibited excellent photocatalytic activity in the degradation of organic pollutants (phenol) in wastewater under visible light irradiation. The enhanced photocatalytic performance when rGO and Pd nanoparticles combined with Bi2MoO6 may be attributed to the reduction of the recombination rate of photogenerated electrons/holes. Specifically, the rGO layer may serve as the electron accepter, which means photogenerated electrons can rapidly transfer to its surface instead of jumping back to the valence band and combining with positive holes. Additionally, the black-body property of graphite-like material contribute the increased harvesting capacity of visible-light photons. Furthermore, palladium nanoparticles distributed on the surface can also be stimulated by visible light photons due to the surface plasmon resonance effect, which further increased the utilization efficiency of visible light irradiation. This work opens a new possibility for efficient removal of phenolic compounds in wastewater via visible light-driven photocatalysis in the presence of a Pd-rGO- Bi2MoO6 ternary composite. (C) 2017 Elsevier B.V. All rights reserved.