• 文献标题:   Accordion-like graphene by a facile and green synthesis method reinforcing polyolefin nanocomposites
  • 文献类型:   Article
  • 作  者:   GAO WS, LI JG, YAN XJ, ZHU BC, JIA JJ, HUANG AP, XIE KF, BAI YX
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   7
  • DOI:   10.1039/c7ra04139j
  • 出版年:   2017

▎ 摘  要

Herein, accordion-like graphene with a large specific surface area, efficient reduction degree and designed functional groups was successfully synthesized via thermal expansion exfoliation of alkylated graphite oxide at relatively low temperature (below 170 degrees C) without any auxiliary equipment. This functional graphene (M-LTRGO) displayed an improved compatibility and interfacial interaction with polyolefin matrix. The graphene-reinforced polyolefin (including polypropylene and polyethylene) nanocomposites exhibited better mechanical strength and thermal stability than the neat and parallel graphene-reinforced polyolefin nanocomposites. The tensile breaking strength of random polypropylene (PPR) and linear low-density polyethylene (LLDPE) increased by 42.77% and 58.59%, respectively, after their incorporation at a loading amount of 0.5 wt%. Into M-LTRGO that is much more stronger than other graphene counterparts obtained via double screw melting compounding. This method provides a new route for the large-scale and green production of functional graphene, endowing the nanocomposites with various functional properties and enhanced mechanical performance, and may have great potential applications in structural engineering plastic and biomedical, soft protection, special packaging, and biotechnological areas.