• 文献标题:   Probing the Bonding in Nitrogen-Doped Graphene Using Electron Energy Loss Spectroscopy
  • 文献类型:   Article
  • 作  者:   NICHOLLS RJ, MURDOCK AT, TSANG J, BRITTON J, PENNYCOOK TJ, KOOS A, NELLIST PD, GROBERT N, YATES JR
  • 作者关键词:   ndoped, nitrogen doping, cvd graphene, stem, eels, modeling
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Oxford
  • 被引频次:   45
  • DOI:   10.1021/nn402489v
  • 出版年:   2013

▎ 摘  要

Precise control of graphene properties is an essential step toward the realization of future graphene devices. Defects, such as individual nitrogen atoms, can strongly influence the electronic structure of graphene. Therefore, state-of-the-art characterization techniques, in conjunction with modern modeling tools, are necessary to identify these defects and fully understand the synthesized material. We have directly visualized individual substitutional nitrogen dopant atoms in graphene using scanning transmission electron microscopy and conducted complementary electron energy loss spectroscopy experiments and modeling which demonstrates the influence of the nitrogen atom on the carbon K-edge.