▎ 摘　　要

Elastic material instabilities are precursors to failure in defect-free graphene single crystals. Elastic instabilities originate from softening in the material response (decay of tangent moduli) induced by dilatant mechanical deformation. Here, we characterize the softening in the constitutive response of graphene within the framework of hyperelasticity based on symmetry-invariants of the two-dimensional logarithmic strain tensor E-(0). The use of symmetry-invariants provides significant functional simplification in representation of the strain energy function of graphene; ab initio calculations of deformation energy are well-fit using half the number of elastic constants of previous formulations. For a set of large homogeneous deformations comprising uniaxial stretch/stress along the armchair and the zigzag directions, and equi-biaxial tension, stress values predicted by the model compare well with those directly calculated from ab initio solutions. Using acoustic tensor analysis, we show that the constitutive model accurately captures elastic stability limits for a number of biaxial deformation modes, providing results that compare well with independent phonon calculations carried out using linear response density functional perturbation theory. In the case of equi-biaxial deformation, an elastic shearing instability is identified which occurs prior to the configuration of maximum true stress. Potential implications of the present results on the interpretation of limiting deformations achieved in nanoindentation experiments are briefly noted.