• 文献标题:   Facile synthesis of holey graphene-supported Pt catalysts for direct methanol electro-oxidation
  • 文献类型:   Article
  • 作  者:   ZHOU LH, WANG YX, TANG J, LI JX, WANG SL, WANG Y
  • 作者关键词:   holey graphene, pt, catalyst, methanol, electrooxidation
  • 出版物名称:   MICROPOROUS MESOPOROUS MATERIALS
  • ISSN:   1387-1811 EI 1873-3093
  • 通讯作者地址:   East China Univ Sci Technol
  • 被引频次:   13
  • DOI:   10.1016/j.micromeso.2017.03.061
  • 出版年:   2017

▎ 摘  要

A simple synthetic method was developed to produce holey graphene with in-plane nanopores by a fast thermal expansion of graphene oxide (GO) in air and further thermal reduction in N-2 flow at 900 degrees C. The as-synthesized holey graphene nanosheets (HGN) shows meso-macroporous structure and higher surface area than chemically reduced graphene oxide (CRGO) by using hydrazine hydrate. The catalysts of HGN-900 supported Pt nanoparticles (Pt/HGN-900) were further prepared through in-situ chemical co-reduction and applied in the electro-oxidation of methanol. The electrocatalytic performance of catalysts was investigated by cyclic voltammetry (CV) and chronoamperometry (CA) analysis. The results indicate that the catalytic activity of Pt/HGN-10min-900 (377.5 mA mg(pt)(-1)) is bout 1.83 and 2.77 times higher than that of Pt/CRGO-900 (206.1 mA mg(pt)(-1)) and Pt/XC-72 (136.2 mA mg(pt)(-1)) catalysts in 0.5 mol L-1 H2SO4 and 1.0 mol L-1 CH3OH, and Pt/HGN-900 catalysts show higher stable current density compared to that of Pt/XC-72 and Pt/CRGO-900 catalysts. (C) 2017 Elsevier Inc. All rights reserved.