• 文献标题:   Blown Bubble Assembly of Graphene Oxide Patches for Transparent Electrodes in Carbon-Silicon Solar Cells
  • 文献类型:   Article
  • 作  者:   WU ST, YANG YB, LI YT, WANG CH, XU WJ, SHI EZ, ZOU MC, YANG LS, YANG XD, LI Y, CAO AY
  • 作者关键词:   graphene oxide sheet, blown bubble assembly, thermal annealing hybrid film, patche, transparent electrode, solar cell
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Peking Univ
  • 被引频次:   1
  • DOI:   10.1021/acsami.5b08646
  • 出版年:   2015

▎ 摘  要

Graphene oxide (GO) sheets have a strong tendency to aggregate, and their interfaces can impose limitations on the electrical conductivity, which would hinder practical applications. Here, we present a blown bubble film method to assemble GO sheets with a uniform distribution over a large area and further interconnect individual GO sheets by transforming the bubble film into graphitized carbon. A conventional polymer was used to facilitate the bubble blowing process and disperse GO sheets in the bubble. Then, the bubble film was annealed on a Cu substrate, resulting in a highly transparent reduced GO (RGO) carbon hybrid structure consisting of RGO patches well adhered to the carbon film. We fabricated RGO carbon/Si solar cells with power conversion efficiencies up to 6.42%, and the assembled RGO patches hybridized with carbon film can form an effective junction with Si, indicating potential applications in thin film electronic devices and photovoltaics.