• 文献标题:   Coagulation-assisted preparation of graphene oxide/polyamide 6 composites
  • 文献类型:   Article
  • 作  者:   WU J, GAN H, LIU HB
  • 作者关键词:   graphene oxide, polyamide 6, coagulationassisted tactic, dispersion, reinforcing mechanism
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.matchemphys.2021.124579 EA APR 2021
  • 出版年:   2021

▎ 摘  要

Graphene oxide (GO) reinforced polyamide 6 (PA 6) composites are promising lightweight materials for engineering applications. However, the industrial development of GO/PA 6 composites has been severely impeded by the complicated preparation process and undesirable dispersion of GO in PA 6. In this work, an economical and time costless ?coagulation-assisted? tactic was proposed to implement the batch preparation of GO/PA 6 composites with uniform dispersion of GO and superior comprehensive performances simultaneously. The tensile test indicated that GO/PA 6 composites showed higher tensile strength (66.31 MPa) and Young?s modulus (1.17 GPa) values than pristine PA 6 (40.81 MPa and 0.46 GPa, respectively) even at very low GO loading (0.6 wt%). Furthermore, better thermal stability of GO/PA 6 composites was obtained, the onset and maximum thermal degradation temperature of GO/PA 6 composites maximally increased by 5.21 and 12.38 ?C, respectively. Additionally, GO were confirmed to induce the nucleation of crystallization of PA 6 as heterogeneous nucleus and promote the formation of ?1-form crystals in PA 6. More significantly, this ?coagulation-assisted? tactic can also be employed in other nanofiller reinforced polymer composites for a wide variety of applications.