• 文献标题:   Epitaxial synthesis of graphene on 4H-SiC by microwave plasma chemical vapor deposition
  • 文献类型:   Article
  • 作  者:   ZHANG XM, YAN CL, ZENG CH, SUN TY, XING Z, SHI WH, WANG YQ, PANG C, ZHANG BS
  • 作者关键词:   graphene, epitaxial growth, mpcvd, 4hsic, hall mobility
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:  
  • 通讯作者地址:   Changchun Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1088/2053-1591/abcb3a
  • 出版年:   2020

▎ 摘  要

Epitaxial graphene (EG) on semi-insulating SiC prepared by a thermal decomposition method is the most promising strategy for graphene application in large-scale integrated circuits due to compatibility with current semiconductor processes. In this study, high-quality few-layer graphene (FLG) was epitaxially grown on the semi-insulating on-axis 4H-SiC by microwave plasma chemical vapor deposition (MPCVD). Both sides of the SiC substrate were etched with H-2 plasma at similar to 1000 degrees C to promote the nucleation and the growth of graphite before epitaxial growth. The surface morphology and properties of EG on SiC (0001) were measured by energy-dispersive x-ray (EDX), x-ray photoelectron spectrogram (XPS), and atomic force microscope (AFM). The qualities of EG grown on the two surfaces of SiC at various temperatures were checked by Raman spectroscopy. Furthermore, the EG growth was controlled by the effect of Ar plasma in the MPCVD and the few-layer (1-3 layers) high-quality EG films were formed on SiC (000 (1) over bar). The room temperature Hall mobility of EGs up to 2790 cm(2) V-1 s(-1) on SiC(000 (1) over bar) was realized.