• 文献标题:   The Relationship between the Specific Surface Area of a Nanofiller and the Elastic Modulus for Polymer/Graphene Nanocomposites
  • 文献类型:   Article
  • 作  者:   KOZLOV GV, DOLBIN IV
  • 作者关键词:   nanocomposite, graphene, aggregation, tactoid, specific surface area, percolation threshold, elastic modulu
  • 出版物名称:   PROTECTION OF METALS PHYSICAL CHEMISTRY OF SURFACES
  • ISSN:   2070-2051 EI 2070-206X
  • 通讯作者地址:   Kabardino Balkarian State Univ
  • 被引频次:   0
  • DOI:   10.1134/S2070205120030211
  • 出版年:   2020

▎ 摘  要

The relationship between the effective (real) specific surface area of the nanofiller and the elastic modulus for polymer/graphene nanocomposites is studied. The process of aggregation of a graphene 2D nanofiller (the formation of its tactoids) leads to a decrease in its effective specific surface area, since the surface of graphene plates inside the tactoid, which does not interact with the polymer matrix, does not affect the formation of the properties of nanocomposites. This effect is realized only above the percolation threshold of the nanofiller. An interpretation is proposed that allows estimating the number of graphene plates in one tactoid. Further calculations allow the determination of the effective specific surface area of the nanofiller and the degree of reinforcement of the nanocomposite.