• 文献标题:   Few layer graphene nanosheets from kinnow peel waste for high-performance supercapacitors: A comparative study with three different electrolytes
  • 文献类型:   Article
  • 作  者:   PATHAK M, TATRARI G, KARAKOTI M, PANDEY S, SAHU PS, SAHA B, SAHOO NG
  • 作者关键词:   kinnow peel waste kpw, supercapacitor, graphene nanosheet, specific capacitance
  • 出版物名称:   JOURNAL OF ENERGY STORAGE
  • ISSN:   2352-152X EI 2352-1538
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.est.2022.105729
  • 出版年:   2022

▎ 摘  要

Utilization of carbonaceous waste into energy storage applications not only solves the problem of waste man-agement but also promotes the circular economy. Any carbonaceous material with a high surface area and sheet -like nanostructure facilitates fast-ion transport due to which it can act as a suitable candidate for the electrode material in Supercapacitors. This work reports the preparation of few-layer graphene nanosheets from fruit waste: kinnow peel waste (KPW) for the first time, via two-step pyrolysis with activation using KCl as the activating agent followed by probe sonication. The confirmation of few-layer graphene (FLG) nanosheets from KPW was done with the help of RAMAN, XRD, FT-IR, SEM, and TEM. The high surface area with the presence of both the meso and micropores in synthesized FLG nanosheets was confirmed with the help of BET. The KPW-derived few-layer graphene (KPW-FLG) nanosheets were further investigated for high-performance super -capacitors by fabricating three different supercapacitor devices (SCs); SC-1, SC-2, and SC-3 corresponded to 6 M KOH, 1 M H2SO4 and 1 M H3PO4 respectively. The ideal and reversible capacitive behavior of the fabricated SC devices was analyzed with the help of Cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) techniques. The SC-2 displayed the highest gravimetric specific capacitance (Cs) value of 642 F/g at a scan rate of 5 mV/s in a 1 M H2SO4 electrolyte with the highest energy density of 48.9 Wh/Kg and better power density of 629.5 W/Kg. Our study revealed that the KPW-FLG can be used as the potential candidate for electrode material in fabricating the high-performance supercapacitor which showed the best results in capacitance, charge -discharge, cyclic stability, and energy density with 1 M H2SO4 electrolyte.