• 文献标题:   Sandwiched Thin-Film Anode of Chemically Bonded Black Phosphorus/Graphene Hybrid for Lithium-Ion Battery
  • 文献类型:   Article
  • 作  者:   LIU HW, ZOU YQ, TAO L, MA ZL, LIU DD, ZHOU P, LIU HB, WANG SY
  • 作者关键词:  
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   37
  • DOI:   10.1002/smll.201700758
  • 出版年:   2017

▎ 摘  要

A facile vacuum filtration method is applied for the first time to construct sandwich-structure anode. Two layers of graphene stacks sandwich a composite of black phosphorus (BP), which not only protect BP from quickly degenerating but also serve as current collector instead of copper foil. The BP composite, reduced graphene oxide coated on BP via chemical bonding, is simply synthesized by solvothermal reaction at 140 degrees C. The sandwiched film anode used for lithium-ion battery exhibits reversible capacities of 1401 mAh g(-1) during the 200th cycle at current density of 100 mA g(-1) indicating superior cycle performance. Besides, this facile vacuum filtration method may also be available for other anode material with well dispersion in N-methyl pyrrolidone (NMP).