• 文献标题:   Detection of nitrite in water using Glycine-modified nanocarbon and Au nanoparticles co-modified flexible laser-induced graphene electrode
  • 文献类型:   Article
  • 作  者:   WANG JX, SHAN XH, XUE Q, LIU Y, LIU ZY, HE L, WANG XL, ZHU CC
  • 作者关键词:   nitrite, electrochemical sensor, au nanoparticle, glycine, laserinduced graphene
  • 出版物名称:   INORGANIC CHEMISTRY COMMUNICATIONS
  • ISSN:   1387-7003 EI 1879-0259
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.inoche.2023.110652 EA APR 2023
  • 出版年:   2023

▎ 摘  要

In this work, we firstly developed a laser-induced graphene (LIG) electrode modified by gold nanoparticles (AuNPs) and glycine-modified nanocarbon (Gly-C), and used it to detect nitrite by linear scanning voltammetry. The physical and electrochemical characteristics of the electrodes were characterized using scanning electron microscopy, energy dispersive spectroscopy analysis, fourier transform infrared spectroscopy, and contact angle analysis. Our findings demonstrated that the electrocatalytic oxidation of nitrite can be enhanced by the successful loading of AuNPs, and Gly-C enhances electrode hydrophilicity and promotes nitrite adsorption capacity of the electrode surface. Under optimal conditions, the linear of the sensor is 7 - 700 & mu;g/L and 700 - 1050 & mu;g/L, and the detection limit is 0.84 & mu;g/L. The anti-interference, repeatability, and stability of this sensor are outstanding. Recovery rates of the sensor in the actual groundwater and tap water varied from 94 to 123 %, and the relative standard deviation was less than 6.06 %. Our findings offer a potentially effective method for on-site monitoring of nitrite in aquatic environments.