• 文献标题:   Two-dimensional layered lithium lanthanum titanium oxide/graphene-like composites as electrodes for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   GU B, ZHAN CY, LIU BH, WANG G, ZHANG Q, ZHANG M, SHEN ZR
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1039/d2dt00751g EA APR 2022
  • 出版年:   2022

▎ 摘  要

Perovskite-structured (ABO(3)) lithium lanthanum titanate (LixLa(2-x)/3TiO3, LLTO) is widely used in all solid state lithium ion batteries due to its high ionic conductivity. In this study, a two-dimensional LLTO nanosheet/graphene (LLTO/C) nanosheet composite has been designed as an electrode material for lithium-ion batteries (LIBs). LLTO/C not only exhibits the ionic conductivity properties of perovskite-type LLTO, but the graphene between the layers of LLTO nanosheets also endows the material with additional electronic conductivity. Moreover, LLTO@C-600 exhibits an excellent rate capability as the electrode for delithiation with a high specific capacity of 350 mA h g(-1) at 20 mA g(-1), and 70% of the specific capacity can be maintained at 1.0 A g(-1) after 800 cycles. The excellent electrochemical performances can be attributed to the superior interficial capacitive Li+ storage capability.