▎ 摘　　要

In the present work, 3D mesoporous graphene assembly was fabricated in a hydrothermal process using triethylenetetramine molecules as cross-linkers. And CuO nanoparticles were introduced in the graphene assembly via in-situ photodeposition. Then, a photocatalytic system containing Eosin Y as a sensitizer, graphene assembly as a supporter material and electron transfer channel, and CuO nanoparticles as an active center of H-2 evolution from water was prepared. Meanwhile, photocatalytic hydrogen evolution from water over the as prepared photocatalytic system was explored under visible irradiation. Furthermore, for practical purposes, the durability of the photocatalytic system was also studied. And the photocatalytic mechanism was preliminarily discussed. The experimental results indicate that the as-prepared photocatalytic system is an efficient photocatalyst for visible-light driven H-2 evolution from water. The rate of H-2 evolution over the photocatalytic system is up to 5.85 mmol g(-1) h(-1) under optimal conditions, which is 2.3 times higher than that over reduced graphene oxide loaded with CuO. The 3D porous graphene assembly plays an important role in the photocatalytic process. It can not only efficiently enhance the electron transfer in the photocatalytic system, but also result in fast diffusion of sacrificial reagent and timely release of H-2 bubbles. This work provides us with new possibility for designing an efficient Pt-free visible photocatalyst for H-2 evolution from water. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.